Faraday’s law of electrolysis
The factor s affecting the
quantities of matter liberated during the process of electrolysis were investigated by faraday.
First Law: The mass of a
substance liberated at an electrode is directly proportional to the charge
passing through the electrolyte.
If an electric current I is passed through the
electrolyte for a time t, the amount of charge (q) passed is It. According to
the law, mass of substance liberated (m) is
M
α
q or m=zit
Where Z is constant for the substance being liberated
called as electrochemical equivalent. Its unit is kg C-1.
The
electrochemical equivalent of a substance is defined as the mass of substance liberated
in electrolysis when one coulomb charge is passed through the electrolyte.
Second
Law: The mass of a substance liberated at an
electrode by a given amount of charge is proportional to the chemical
equivalent of the substance.
If E is
the chemical equivalent of a substance, from the second law
mαE